Ryo Yoshida
Self-oscillating polymer gels as novel biomimetic softmaterialsAbstract
We developed "self-oscillating" polymer gels that undergo spontaneous
cyclic swelling–deswelling changes without any on–off switching of
external stimuli, as with heart muscle. The self-oscillating gels were
designed by utilizing the Belousov-Zhabotinsky (BZ) reaction as
oscillating reaction. We have systematically studied these
self-oscillating polymer gels since they were first reported in 1996.
Potential applications of the self-oscillating polymers and gels include
several kinds of functional material systems such as biomimetic
actuators, mass transport systems and functional fluids. For example,
it was demonstrated that an object was autonomously transported in the
tubular self-oscillating gel by the peristaltic pumping motion similar
to an intestine. Further, self-oscillating polymer brush surface like
cilia, vesicles or colloidosomes undergoing cell-like autonomous shape
oscillations with buckling, was prepared. Besides, autonomous sol-gel
oscillation and amoeba-like motion was realized utilizing well-designed block copolymer
solution. In this talk, our recent progress on the self-oscillating
polymer gels is summarized.
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