Željko Čupić
CONTEMPORARY RESEARCH IN OSCILLATORY CATALYTIC REACTIONSAbstract
Numerous processes in physical chemistry and related sciences take place in cycle,
with consecutive alternations in time. Widely known as oscillatory or oscillating
reactions, such processes are explored as nonlinear phenomena, but their potential
in various applications became recognized only recently, almost 100 years after the
discovery of the first homogeneous oscillatory reaction. This lecture will discuss
the results of contemporary research focused on the application of oscillatory
reactions in the design of new materials, devices and technologies. Wide spectrum
of analytical applications of oscillatory reactions was developed, with unexpected
robustness and high sensitivity toward evaluation of pharmaceutically active
compounds. Self-oscillating gels were developed to be used as components of micro
devices (actuators) or to achieve controlled periodic drug delivery. Oscillatory
reactions are also central figure in attempts to develop chemical computing systems
as devices for fast parallel information processing. Advantages of fuel cells with
electro-catalytic oxidations in oscillating regime were reported, too. There are
also examples of other catalytic systems where oscillating dynamic state was found
advantageous over the monotonous catalysis in stable steady state. Most examined
oscillatory catalytic system may be oxidation of CO over Pt, but carbonylation of
alkyne over Pd complexes is the first catalytic system where selectivity
improvement was reported under oscillatory regime.
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